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Author(s):   Walsh, R.; Wells, J.M.
Title:   The Kinetics of the Diels-Alder Addition of Cyclopentadiene to Acetylene and the Decomposition of Norbornadiene
Journal:   Int. J. Chem. Kinet.
Volume:   7
Year:   1975
Reference type:   Journal article
Squib:   1975WAL/WEL319

Reaction:   C2H2 + Cyclopentadiene2,5-Norbornadiene
Reaction order:   2
Temperature:   525 - 756 K
Pressure:  0.13 bar
Rate expression:   5.38x10-14 [cm3/molecule s] e-101437 [±1014 J/mole]/RT
Uncertainty:   1.12
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
525 4.35E-24
550 1.25E-23
575 3.28E-23
600 7.95E-23
625 1.79E-22
650 3.80E-22
675 7.61E-22
700 1.45E-21
725 2.65E-21
750 4.64E-21
756 5.28E-21