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Accessibility information
Author(s):   Yampol'skii, Yu.P.
Title:   Reactivity of Primary and Secondary Carbon-Hydrogen Bonds in Radical Processes
Journal:   React. Kinet. Catal. Lett.
Volume:   2
Year:   1975
Reference type:   Journal article
Squib:   1975YAM449

Reaction:   n-C4H10 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   ·CH3 + D2CH3D + D
Temperature:   980 - 1060 K
Pressure:  6.67E-2 bar
Rate expression:   5.25x10-12 [cm3/molecule s] e-46478 [±8398 J/mole]/RT
Uncertainty:   2.56999993
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
980 1.75E-14
1000 1.96E-14
1025 2.25E-14
1050 2.56E-14
1060 2.69E-14