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Accessibility information
Author(s):   Zellner, R.
Title:   Rate Measurements of Some Bimolecular Reactions of the Hydroxyl Radical over an Extended Temperature Range
Journal:   Mol. Rate Processes, Pap. Symp.
Volume:   7
Year:   1975
Reference type:   Journal article
Squib:   1975ZEL1

Reaction:   ·OH + NH3H2O + NH2
Reaction order:   2
Temperature:   228 - 472 K
Pressure:  1.01 bar
Rate expression:   2.32x10-12 [cm3/molecule s] e-6652 [J/mole]/RT
Bath gas:   H2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
228 6.96E-14
250 9.48E-14
275 1.27E-13
300 1.62E-13
325 1.98E-13
350 2.36E-13
375 2.75E-13
400 3.15E-13
425 3.54E-13
450 3.93E-13
472 4.27E-13