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Accessibility information
Author(s):   Barnard, J.A.; Parrott, T.K.
Title:   Kinetics of the thermal unimolecular reactions of cyclohexene and 4-vinylcyclohexene behind reflected shock waves
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Year:   1976
Reference type:   Journal article
Squib:   1976BAR/PAR2404

Reaction:   4-Vinylcyclohexene1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   927 - 1050 K
Pressure:  1.93 - 2.47 bar
Rate expression:   6.17x1015 [s-1] e-261906 [J/mole]/RT
Uncertainty:   1.54999995
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
927 1.08E1
950 2.45E1
975 5.74E1
1000 1.29E2
1025 2.78E2
1050 5.77E2