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Accessibility information
Author(s):   Barnard, J.A.; Parrott, T.K.
Title:   Kinetics of the thermal unimolecular reactions of cyclohexene and 4-vinylcyclohexene behind reflected shock waves
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Year:   1976
Reference type:   Journal article
Squib:   1976BAR/PAR2404

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1010 - 1190 K
Pressure:  1.69 - 2.99 bar
Rate expression:   1.45x1015 [s-1] e-274378 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1010 9.37E0
1025 1.51E1
1050 3.25E1
1075 6.75E1
1100 1.36E2
1125 2.64E2
1150 5.00E2
1175 9.21E2
1190 1.31E3