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Accessibility information
Author(s):   Bradley, J.N.; Whytock, D.A.; Zaleski, T.A.
Title:   Kinetic study of the reaction of hydrogen atoms with chlorotrifluoromethane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Year:   1976
Reference type:   Journal article
Squib:   1976BRA/WHY2284

Reaction:   CF3Cl + ·CF3 + HCl
Reaction order:   2
Temperature:   538 - 676 K
Pressure:  6.67E-4 - 3.20E-3 bar
Rate expression:   2.82x10-11 [cm3/molecule s] e-36833 [±1837 J/mole]/RT
Uncertainty:   1.45000005
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
538 7.49E-15
550 8.97E-15
575 1.27E-14
600 1.75E-14
625 2.36E-14
650 3.10E-14
675 3.99E-14
676 4.02E-14