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Accessibility information
Author(s):   Cadman, P.; Kirk, A.W.; Trotman-Dickenson, A.F.
Title:   Reactions of chlorine atoms with ethane, propane, isobutane, fluoroethane, 1,1-difluoroethane, 1,1,1-trifluoroethane and cyclopropane
Journal:   J. Chem. Soc. Chem. Commun.
Volume:   72
Page(s):  
Year:   1976
Reference type:   Journal article
Squib:   1976CAD/KIR1027

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1976CAD/KIR1027   C2H6 + ·Cl·C2H5 + HCl  284 - 369   9.55E-11       3426   2.40E-11  2
  1976CAD/KIR1027   C3H8 + ·Cliso-C3H7 + HCl  283 - 369   7.09E-11       1837   3.38E-11  2
  1976CAD/KIR1027   C3H8 + ·Cliso-C3H7 + HCl  283 - 369   0.63       -1488   1.15  2
  Reference reaction:  C3H8 + ·Cl1-C3H7 + HCl 2
  1976CAD/KIR1027   C3H8 + ·Cliso-C3H7 + HCl  283 - 369   6.53       -1896   14.03  2
  Reference reaction:  C2H5F + ·ClHCl + CH3C(·)HF 2
  1976CAD/KIR1027   C3H8 + ·Cl1-C3H7 + HCl  238 - 363   1.12E-10       3326   2.93E-11  2
  1976CAD/KIR1027   iso-C4H10 + ·Cltert-C4H9 + HCl  238 - 363   2.89E-11       1147   1.82E-11  2
  1976CAD/KIR1027   iso-C4H10 + ·Cltert-C4H9 + HCl  252 - 367   0.80       -2278   2.01  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1976CAD/KIR1027   iso-C4H10 + ·Cliso-C4H9 + HCl  238 - 363   8.52E-11       2428   3.20E-11  2
  1976CAD/KIR1027   iso-C4H10 + ·Cliso-C4H9 + HCl  252 - 367   0.89       -998   1.33  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1976CAD/KIR1027   iso-C4H10 + ·Cliso-C4H9 + HCl  238 - 363   2.88       1239   1.75  2
  Reference reaction:  iso-C4H10 + ·Cltert-C4H9 + HCl 2
  1976CAD/KIR1027   CH3CHF2 + ·ClHCl + CH3CF2  283 - 367   2.69E-12       8132   1.01E-13  2
  1976CAD/KIR1027   CH3CHF2 + ·ClHCl + CH3CF2  283 - 367   0.63       -1.22E04   87.43  2
  Reference reaction:  CH3CHF2 + ·ClHCl + CH2CHF2 2
  1976CAD/KIR1027   CH3CHF2 + ·ClHCl + CH2CHF2  283 - 367   4.27E-12       2.04E04   1.15E-15  2
  1976CAD/KIR1027   C2H5F + ·ClHCl + CH2CH2F  283 - 367   7.26E-12       8564   2.29E-13  2
  1976CAD/KIR1027   C2H5F + ·ClHCl + CH3C(·)HF  283 - 367   1.10E-11       3733   2.43E-12  2
  1976CAD/KIR1027   C2H5F + ·ClHCl + CH3C(·)HF  283 - 367   4.07       -4390   23.94  2
  Reference reaction:  CH3CHF2 + ·ClHCl + CH2CHF2 2
  1976CAD/KIR1027   C2H5F + ·ClHCl + CH3C(·)HF  283 - 367   1.48       -4839   10.43  2
  Reference reaction:  C2H5F + ·ClHCl + CH2CH2F 2
  1976CAD/KIR1027   CH3CF3 + ·ClCF3CH2 + HCl  281 - 368   3.32E-12       2.50E04   1.36E-16  2

Search returned 18 records.