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Accessibility information
Author(s):   Cadman, P.; Kirk, A.W.; Trotman-Dickenson, A.F.
Title:   Reactions of chlorine atoms with ethane, propane, isobutane, fluoroethane, 1,1-difluoroethane, 1,1,1-trifluoroethane and cyclopropane
Journal:   J. Chem. Soc. Chem. Commun.
Volume:   72
Page(s):  
Year:   1976
Reference type:   Journal article
Squib:   1976CAD/KIR1027

Reaction:   CH3CHF2 + ClHCl + CH3CF2
Reaction order:   2
Reference reaction:   CH3CHF2 + ClHCl + CH2CHF2
Reference reaction order:   2
Temperature:   283 - 367 K
Rate expression:   6.3x10-1 e12222 [±122 J/mole]/RT
Uncertainty:   1.04999995
Bath gas:   C2F6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
283 1.14E2
300 8.46E1
325 5.80E1
350 4.20E1
367 3.46E1