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Author(s):   Davis, D.D.; Machado, G.; Conaway, B.; Oh, Y.; Watson, R.
Title:   A temperature dependent kinetics study of the reaction of OH with CH3Cl, CH2Cl2, CHCl3, and CH3Br
Journal:   J. Chem. Phys.
Volume:   65
Year:   1976
Reference type:   Journal article
Squib:   1976DAV/MAC1268

Reaction:   CH3Br + ·OHH2O + ·CH2Br
Reaction order:   2
Temperature:   245 - 375 K
Pressure:  2.67E-2 - 0.27 bar
Rate expression:   7.95x10-13 [±7.97x10-14 cm3/molecule s] e-7383 [±8314472 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
245 2.12E-14
250 2.28E-14
275 3.15E-14
300 4.12E-14
325 5.18E-14
350 6.29E-14
375 7.45E-14