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Author(s):   Gaynor, B.J.; Gilbert, R.G.; King, K.D.; Mackie, J.C.
Title:   The isomerization of cycloheptatriene at high temperatures
Journal:   Int. J. Chem. Kinet.
Volume:   8
Year:   1976
Reference type:   Journal article
Squib:   1976GAY/GIL695

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   990 - 1250 K
Pressure:  0.40 - 0.80 bar
Rate expression:   3.98x1013 [s-1] e-213682 [±10726 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
990 2.12E2
1000 2.74E2
1025 5.14E2
1050 9.33E2
1075 1.65E3
1100 2.84E3
1125 4.77E3
1150 7.84E3
1175 1.26E4
1200 1.99E4
1225 3.08E4
1250 4.69E4