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Accessibility information
Author(s):   Howard, C.J.; Evenson, K.M.
Title:   Rate Constants for the Reactions of OH with CH4 and Fluorine, Chlorine, and Bromine Substituted Methanes at 296K
Journal:   J. Chem. Phys.
Volume:   64
Page(s):  
Year:   1976
Reference type:   Journal article
Squib:   1976HOW/EVE197

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1976HOW/EVE197   CCl4 + ·OH → Products  296   <4.00E-15              2
  1976HOW/EVE197   CHCl3 + ·OH·CCl3 + H2O  296   1.01E-13              2
  1976HOW/EVE197   CH4 + ·OH·CH3 + H2O  296   9.51E-15              2
  1976HOW/EVE197   CH3Br + ·OHH2O + ·CH2Br  296   3.50E-14              2
  1976HOW/EVE197   CH3Cl + ·OH·CH2Cl + H2O  296   3.60E-14              2
  1976HOW/EVE197   CH2Cl2 + ·OHCHCl2 + H2O  296   1.55E-13              2
  1976HOW/EVE197   CH2F2 + ·OH·CHF2 + H2O  296   7.80E-15              2
  1976HOW/EVE197   CHFCl2 + ·OH·CCl2F + H2O  296   2.61E-14              2
  1976HOW/EVE197   CHF2Cl + ·OH·CClF2 + H2O  296   3.40E-15              2
  1976HOW/EVE197   CHF3 + ·OH·CF3 + H2O  296   2.01E-16              2
  1976HOW/EVE197   CFCl3 + ·OH → Products  296   <5.00E-16              2
  1976HOW/EVE197   CF2Cl2 + ·OH → Products  296   <4.00E-16              2
  1976HOW/EVE197   CF3Cl + ·OH → Products  296   <7.01E-16              2
  1976HOW/EVE197   CF4 + ·OH → Products  296   <4.00E-16              2
  1976HOW/EVE197   CH3F + ·OH·CH2F + H2O  296   1.60E-14              2
  1976HOW/EVE197   CH2FCl + ·OHH2O + ·CClFH  296   3.70E-14              2

Search returned 16 records.