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Author(s):   Huybrechts, G.; Paternoster, G.; Baetens, P.
Title:   Kinetics of the Diels-Alder Addition of Acrolein to Cyclohexa-1,3-diene and Its Reverse Reaction in the Gas Phase
Journal:   Int. J. Chem. Kinet.
Volume:   8
Year:   1976
Reference type:   Journal article
Squib:   1976HUY/PAT641

Reaction:   CH2=CHCHO + 1,3-Cyclohexadiene → Bicyclo[2.2.2]oct-5-ene-2carboxaldehyde,(1α.2β,4α)-
Reaction order:   2
Temperature:   486 - 571 K
Pressure:  7.33E-2 - 0.32 bar
Rate expression:   7.42x10-16 [cm3/molecule s] e-81482 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
486 1.30E-24
500 2.28E-24
525 5.80E-24
550 1.36E-23
571 2.61E-23