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Author(s):   Martens, G.J.; Godfroid, M.; Delvaux, J.; Verbeyst, J.
Title:   Gas-phase hydrogen abstraction from asymmetrically halogenated ethanes by chlorine atoms
Journal:   Int. J. Chem. Kinet.
Volume:   8
Year:   1976
Reference type:   Journal article
Squib:   1976MAR/GOD153

Reaction:   CH3CHF2 + ·ClHCl + CH3CF2
Reaction order:   2
Reference reaction:   CH3CHF2 + ·ClHCl + CH2CHF2
Reference reaction order:   2
Temperature:   264 - 333 K
Pressure:  1.01 bar
Rate expression:   1.48 e10144 [±62359 J/mole]/RT
Uncertainty:   1.01999998
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
264 1.50E2
275 1.25E2
300 8.64E1
325 6.32E1
333 5.77E1