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Author(s):   Masson, D.; Richard, C.; Martin, R.
Title:   Thermal Isomerization of Cis- or Trans-2-Butene. The Unimolecular Elimination of Hydrogen from Cis-2-Butene Around 500oC
Journal:   Int. J. Chem. Kinet.
Volume:   8
Year:   1976
Reference type:   Journal article
Squib:   1976MAS/RIC37

Reaction:   (Z)-2-C4H81,3-Butadiene + H2
Reaction order:   1
Temperature:   753 - 823 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   1.0x1013 [s-1] e-274378 [±8223 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   (Z)-2-C4H8
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
753 9.27E-7
775 3.22E-6
800 1.22E-5
823 3.85E-5