Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Parkes, D.A.; Quinn, C.P.
Title:   Study of the Spectra and Recombination Kinetics of Alkyl Radicals by Molecular Modulation Spectrometry. Part 2. The Recombination of Ethyl, Isopropyl and t-Butyl Radicals at Room Temperature and t-Butyl Radicals between 250 and 450 K
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Year:   1976
Reference type:   Journal article
Squib:   1976PAR/QUI1952

Reaction:   ·C2H5 + ·C2H5n-C4H10
Reaction order:   2
Reference reaction:   ·C2H5 + ·C2H5C2H6 + C2H4
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.3x10-11 [±2.99x10-12 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.