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Accessibility information
Author(s):   Atkinson, R.; Perry, R.A.; Pitts, J.N., Jr.
Title:   Rate Constants for the Reaction of the OH Radical with CH3SH and CH3NH2 over the Temperature Range 299-426oK
Journal:   J. Chem. Phys.
Volume:   66
Page(s):  
Year:   1977
Reference type:   Journal article
Squib:   1977ATK/PER1578

Reaction:   CH3NH2 + ·OH → Products
Reaction order:   2
Temperature:   299 - 426 K
Pressure:  6.67E-2 - 0.13 bar
Rate expression:   1.02x10-11 [cm3/molecule s] e1904 [±1255 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
299 2.19E-11
300 2.19E-11
325 2.06E-11
350 1.96E-11
375 1.88E-11
400 1.81E-11
425 1.75E-11
426 1.75E-11