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Accessibility information
Author(s):   Baldwin, A.C.; Barker, J.R.; Golden, D.M.; Hendry, D.G.
Title:   Photochemical smog. Rate parameter estimates and computer simulations
Journal:   J. Phys. Chem.
Volume:   81
Year:   1977
Reference type:   Journal article
Squib:   1977BAL/BAR2483

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   1.58x1015 [s-1] e-66516 [±3991 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   N2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 3.47E3
300 4.14E3
325 3.22E4
350 1.87E5
375 8.58E5
400 3.26E6
425 1.06E7
450 3.01E7