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Author(s):   Bell, T.N.; Perkins, K.A.; Perkins, P.G.
Title:   The chlorination of paraffin hydrocarbons. Calculation of the activation energies and A factors for reactions in the total chlorination of methane
Journal:   J. Phys. Chem.
Volume:   81
Page(s):   2610 - 2614
Year:   1977
Reference type:   Journal article
Squib:   1977BEL/PER2610-2614

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1977BEL/PER2610-2614   CCl4 + ·Cl·CCl3 + Cl2  350 - 450   1.23E-10       1.01E05      2
  1977BEL/PER2610-2614   CHCl3 + ·Cl·CCl3 + HCl  350 - 450   4.78E-12       1.36E04      2
  1977BEL/PER2610-2614   CHCl3 + ·ClCHCl2 + Cl2  350 - 450   3.32E-11       1.11E05      2
  1977BEL/PER2610-2614   CH3Cl + ·Cl·CH3 + Cl2  350 - 450   7.09E-12       1.13E05      2
  1977BEL/PER2610-2614   CH2Cl2 + ·Cl·CH2Cl + Cl2  350 - 450   1.10E-11       1.21E05      2
  1977BEL/PER2610-2614   ·CCl3 + HClCHCl3 + ·Cl  305 - 405   2.51E-13       4.29E04      2
  1977BEL/PER2610-2614   ·CH2Cl + Cl2CH2Cl2 + ·Cl  305 - 405   7.59E-13       2.36E04      2

Search returned 7 records.