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Accessibility information
Author(s):   Bell, T.N.; Perkins, K.A.; Perkins, P.G.
Title:   The chlorination of paraffin hydrocarbons. Calculation of the activation energies and A factors for reactions in the total chlorination of methane
Journal:   J. Phys. Chem.
Volume:   81
Page(s):   2610 - 2614
Year:   1977
Reference type:   Journal article
Squib:   1977BEL/PER2610-2614

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1977BEL/PER2610-2614   CCl4 + ·Cl·CCl3 + Cl2  350 - 450   1.23E-10       1.01E05      2
  1977BEL/PER2610-2614   CHCl3 + ·Cl·CCl3 + HCl  350 - 450   4.78E-12       1.36E04      2
  1977BEL/PER2610-2614   CHCl3 + ·ClCHCl2 + Cl2  350 - 450   3.32E-11       1.11E05      2
  1977BEL/PER2610-2614   CH3Cl + ·Cl·CH3 + Cl2  350 - 450   7.09E-12       1.13E05      2
  1977BEL/PER2610-2614   CH2Cl2 + ·Cl·CH2Cl + Cl2  350 - 450   1.10E-11       1.21E05      2
  1977BEL/PER2610-2614   ·CCl3 + HClCHCl3 + ·Cl  305 - 405   2.51E-13       4.29E04      2
  1977BEL/PER2610-2614   ·CH2Cl + Cl2CH2Cl2 + ·Cl  305 - 405   7.59E-13       2.36E04      2

Search returned 7 records.