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Author(s):   Bigley, D.B.; Weatherhead, R.H.; May, R.W.
Title:   Studies in Decarboxylation. Part 10. Effect of β-Substituents on the Rate of Gas-phase Decarboxylation of ββββπβ-Unsaturated Acids
Journal:   J. Chem. Soc. Perkin Trans. 2
Year:   1977
Reference type:   Journal article
Squib:   1977BIG/WEA745

Reaction:   1-Cyclooctene-1-acetic acid, α,α-dimethyl- → CO2 + Cyclooctane,(1-methylethylidene)-
Reaction order:   1
Temperature:   500 K
Pressure:  6.67E-2 - 0.67 bar
Rate expression:   1.66x10-4 [s-1]
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

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