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Accessibility information
Author(s):   Clyne, M.A.A.; Monkhouse, P.B.
Title:   Atomic Resonance Fluorescence for Rate Constants of Rapid Bimolecular Reactions. Part 5. Hydrogen Atom Reactions; H +NO2 and H + O3
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   73
Year:   1977
Reference type:   Journal article
Squib:   1977CLY/MON298

Reaction:   NO2 + ·OH + NO
Reaction order:   2
Temperature:   298 - 653 K
Pressure:  4.00E-3 bar
Rate expression:   4.8x10-10 [cm3/molecule s] e-3334 [±600 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.25E-10
300 1.26E-10
325 1.40E-10
350 1.53E-10
375 1.65E-10
400 1.76E-10
425 1.87E-10
450 1.97E-10
475 2.06E-10
500 2.15E-10
525 2.24E-10
550 2.31E-10
575 2.39E-10
600 2.46E-10
625 2.53E-10
650 2.59E-10
653 2.60E-10