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Author(s):   Huybrechts, G.; Luyckx, L.; Vandenboom, Th.; Van Mele, B.
Title:   Thermal Dimerization of 1,3-Butadiene: Kinetics of the Formation of cis, cis-Cycloocta-1,5-diene
Journal:   Int. J. Chem. Kinet.
Volume:   9
Page(s):  
Year:   1977
Reference type:   Journal article
Squib:   1977HUY/LUY283

Reaction:   1,3-Butadiene + 1,3-Butadiene → 4-Vinylcyclohexene
Reaction order:   2
Temperature:   464 - 557 K
Pressure:  6.53E-2 - 0.60 bar
Rate expression:   1.48x10-14 [cm3/molecule s] e-102268 [J/mole]/RT
Bath gas:   1,3-Butadiene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
464 4.55E-26
475 8.40E-26
500 3.07E-25
525 9.89E-25
550 2.87E-24
557 3.80E-24