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Author(s):   Moortgat, G.K.; Slemr, F.; Warneck, P.
Title:   Kinetics and Mechanism of the Reaction H + CH3ONO
Journal:   Int. J. Chem. Kinet.
Volume:   9
Year:   1977
Reference type:   Journal article
Squib:   1977MOO/SLE249

Reaction:   CH3ONO + CH3OH + NO
Reaction order:   2
Reference reaction:   CH3ONO + → Products
Temperature:   223 - 398 K
Pressure:  2.00E-3 - 5.33E-3 bar
Rate expression:   2.03x10-13 [±3.99x10-14 cm3/molecule s] e-7949 [±477 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
223 2.78E-15
225 2.89E-15
250 4.42E-15
275 6.26E-15
300 8.37E-15
325 1.07E-14
350 1.32E-14
375 1.58E-14
398 1.83E-14