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Author(s):   Schliebs, R.; Knoll, H.; Scherzer, K.
Title:   The Thermal and Initiated Thermal Decomposition of Biacetyl-d6
Journal:   Int. J. Chem. Kinet.
Volume:   9
Year:   1977
Reference type:   Journal article
Squib:   1977SCH/KNO349

Reaction:   (CH3N)2 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   ·CH3 + CD3C(O)C(O)CD3 → Other Products + CH3D
Reference reaction order:   2
Temperature:   524 - 565 K
Pressure:  0.22 - 0.38 bar
Rate expression:   1.0 e5022 [±2511 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
524 3.17E0
525 3.16E0
550 3.00E0
565 2.91E0