Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Smith, G.G.; Mutter, L.; Todd, G.P.
Title:   Steric Effects in Homogeneous Gas-Phase Reactions. Pyrolysis of Isopropyl Esters
Journal:   J. Org. Chem.
Volume:   42
Year:   1977
Reference type:   Journal article
Squib:   1977SMI/MUT44

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1977SMI/MUT44   ClCH2C(O)OCH(CH3)2CH2ClCOOH + CH3CH=CH2  651   0.01              1
  1977SMI/MUT44   CH3COOCH(CH3)2CH3C(O)OH + CH3CH=CH2  651   5.93E-03              1
  1977SMI/MUT44   iso-C3H7C(O)OCH(CH3)2iso-C3H7COOH + CH3CH=CH2  651   6.81E-03              1
  1977SMI/MUT44   C2H5C(O)OCH(CH3)2C2H5COOH + CH3CH=CH2  651   6.10E-03              1
  1977SMI/MUT44   n-C3H7C(O)OCH(CH3)2n-C3H7COOH + CH3CH=CH2  651   5.93E-03              1
  1977SMI/MUT44   n-C5H11C(O)OCH(CH3)2CH3CH=CH2 + CH3(CH2)4COOH  651   6.03E-03              1
  1977SMI/MUT44   Benzeneacetic acid 1-methylethyl esterBenzeneacetic acid + CH3CH=CH2  651   8.13E-03              1
  1977SMI/MUT44   tert-C4H9C(O)OCH(CH3)2tert-C4H9COOH + CH3CH=CH2  651   7.67E-03              1
  1977SMI/MUT44   (C2H5)2CHC(O)OCH(CH3)2(C2H5)2CHCOOH + CH3CH=CH2  651   6.97E-03              1
  1977SMI/MUT44   n-C3H7CH(CH3)C(O)OCH(CH3)2n-C3H7CH(CH3)COOH + CH3CH=CH2  651   6.89E-03              1
  1977SMI/MUT44   CH3OCH2C(O)OCH(CH3)2 → CH3CH=CH2 + CH3OCH2COOH  651   6.87E-03              1
  1977SMI/MUT44   CH3CH=CHC(O)OCH(CH3)2CH3CH=CH2 + CH3CH=CHCOOH  651   7.10E-03              1
  1977SMI/MUT44   n-C4H9C(O)OCH(CH3)2n-C4H9COOH + CH3CH=CH2  651   5.97E-03              1
  1977SMI/MUT44   Benzenepropanoic acid 1-methylethyl ester → CH3CH=CH2 + Benzenepropanoic acid  651   7.36E-03              1
  1977SMI/MUT44   tert-C4H9CH2C(O)OCH(CH3)2 → CH3CH=CH2 + (CH3)3CCH2COOH  651   5.96E-03              1
  1977SMI/MUT44   (n-C3H7)2CHC(O)OCH(CH3)2 → (n-C3H7)2CHCOOH + CH3CH=CH2  651   6.89E-03              1
  1977SMI/MUT44   Benzeneacetic acid, α-phenyl-, 1-methylethyl ester → CH3CH=CH2 + Benzeneacetic acid, α-phenyl-  651   0.01              1
  1977SMI/MUT44   2-Propenoic acid, 3-phenyl-, 1-methylethyl ester,(E)- → CH3CH=CH2 + (E)-3-Phenyl-2-propenoic acid  651   8.13E-03              1

Search returned 18 records.