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Accessibility information
Author(s):   Zabel, V.F.
Title:   Der Thermische Zerfall von Chlorierten Athylenen in der Gasphase I. Tetrachloroathylen und Trichloroathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Page(s):   232 - 240
Year:   1977
Reference type:   Journal article
Squib:   1977ZAB232-240

Reaction:   C2Cl4 → Products
Reaction order:   2
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   1.58x10-7 [cm3/molecule s] e-212547 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Other
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Shock tube measurement.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1450 3.48E-15
1475 4.69E-15
1500 6.26E-15
1525 8.28E-15
1550 1.08E-14
1575 1.41E-14
1600 1.82E-14
1625 2.32E-14
1650 2.95E-14
1675 3.71E-14
1700 4.65E-14
1725 5.78E-14
1750 7.14E-14
1775 8.78E-14
1800 1.07E-13
1825 1.30E-13
1850 1.57E-13
1875 1.89E-13
1900 2.26E-13