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Accessibility information
Author(s):   Amin, H.B.; Taylor, R.
Title:   Electrophilic aromatic reactivities via pyrolysis of 1-arylethyl esters. Part 17. The reactivity of the 2- and 3-positions of benzo[b]furan and of all positions in benzo[b]thiophen
Journal:   J. Chem. Soc. Faraday Trans. 2
Year:   1978
Reference type:   Journal article
Squib:   1978AMI/TAY1053

Reaction:   2-Benzofuranmethanol, α-methyl-, acetate → CH3C(O)OH + Benzofuran, 2-ethenyl-
Reaction order:   1
Temperature:   64.00 - 687 K
Rate expression:   5.62x1012 [s-1] e-180424 [±3617 J/mole]/RT
Uncertainty:   2.1400001
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
64.00 3.14E-135
100 3.22E-82
150 8.35E-51
200 4.25E-35
250 1.13E-25
300 2.17E-19
350 6.66E-15
400 1.55E-11
450 6.41E-9
500 7.97E-7
550 4.12E-5
600 1.10E-3
650 1.78E-2
687 1.08E-1