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Author(s):   Chuchani, G.; Martin, I.; Fraile, G.; Lingstuyl, O.; Diaz, M.J.
Title:   Kinetics of the Gas-Phase Elimination of Isopropyl α-Substituted Acetates
Journal:   Int. J. Chem. Kinet.
Volume:   10
Year:   1978
Reference type:   Journal article
Squib:   1978CHU/MAR893

Reaction:   iso-C4H9C(O)OCH(CH3)2CH3CH=CH2 + iso-C4H9COOH
Reaction order:   1
Temperature:   599 - 629 K
Rate expression:   1.02x1013 [s-1] e-189570 [±1896 J/mole]/RT
Uncertainty:   1.35000002
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
599 3.01E-4
600 3.20E-4
625 1.46E-3
629 1.85E-3