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Accessibility information
Author(s):   Emel'kin, V.A.; Marusin, V.V.
Title:   ESR investigation of the interaction of atomic nitrogen with chlorine
Journal:   Kinet. Catal.
Volume:   19
Year:   1978
Reference type:   Journal article
Squib:   1978EME/MAR1123

Reaction:   Cl2 + NNCl + ·Cl
Reaction order:   2
Temperature:   293 - 773 K
Pressure:  2.27E-3 - 5.33E-3 bar
Rate expression:   5.0x10-12 [cm3/molecule s] e-24112 [±8314472 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   Cl2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 2.51E-16
300 3.17E-16
325 6.66E-16
350 1.26E-15
375 2.19E-15
400 3.55E-15
425 5.44E-15
450 7.94E-15
475 1.12E-14
500 1.51E-14
525 1.99E-14
550 2.56E-14
575 3.22E-14
600 3.98E-14
625 4.83E-14
650 5.77E-14
675 6.81E-14
700 7.94E-14
725 9.15E-14
750 1.05E-13
773 1.17E-13