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Accessibility information
Author(s):   Graham, R.A.; Winer, A.M.; Pitts, J.N., Jr.
Title:   Pressure and Temperature Dependence of the Unimolecular Decomposition of HO2NO2
Journal:   J. Chem. Phys.
Volume:   68
Year:   1978
Reference type:   Journal article
Squib:   1978GRA/WIN4505

Reaction:   HO2NO2 → Products
Reaction order:   2
Temperature:   261 - 295 K
Pressure:  1.33E-4 - 9.33E-3 bar
Rate expression:   5.2x10-6 [cm3/molecule s] e-83145 [±2494 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
261 1.19E-22
275 8.38E-22
295 9.86E-21