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Author(s):   Jourdain, J.-L.; Le Bras, G.; Combourieu, J.
Title:   Etude cinetique des reactions du 1,1,1 trifluoro. 2. Chloroethane avec les atomes de chlore et d'oxygene
Journal:   J. Chim. Phys.
Volume:   75
Year:   1978
Reference type:   Journal article
Squib:   1978JOU/LEB318

Reaction:   CF3CH2Cl + ·OH + CF3CHCl
Reaction order:   2
Temperature:   393 - 621 K
Pressure:  9.33E-4 - 2.67E-3 bar
Rate expression:   2.61x10-12 [cm3/molecule s] e-21784 [±2178 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 3.32E-15
400 3.73E-15
425 5.48E-15
450 7.72E-15
475 1.05E-14
500 1.38E-14
525 1.77E-14
550 2.22E-14
575 2.74E-14
600 3.31E-14
621 3.84E-14