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Accessibility information
Author(s):   Kuznetsov, V.A.; Kashireninov, O.E.
Title:   Competing reactions in a dilute diffusion flame. III. Kinetics of the interaction of magnesium with fluorine
Journal:   Russ. J. Phys. Chem. (Engl. Transl.)
Volume:   52
Page(s):   195 - 197
Year:   1978
Reference type:   Journal article
Squib:   1978KUZ/KAS195-197

Reaction:   Mg + F2·F + MgF
Reaction order:   2
Temperature:   873 - 1070 K
Pressure:  3.33E-3 - 4.53E-2 bar
Rate expression:   3.65x10-10 [±1.83x10-11 cm3/molecule s] e-56455 [±6211 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
873 1.53E-13
875 1.56E-13
900 1.93E-13
925 2.37E-13
950 2.87E-13
975 3.45E-13
1000 4.11E-13
1025 4.85E-13
1050 5.68E-13
1070 6.41E-13