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Author(s):   Marquaire, P.M.; Come, G.M.
Title:   Non Quasi-Stationary State Pyrolysis. Kinetic Parameters of Neopentane Pyrolysis Mechanism
Journal:   React. Kinet. Catal. Lett.
Volume:   9
Year:   1978
Reference type:   Journal article
Squib:   1978MAR/COM171

Reaction:   neo-C5H12 + ·CH3CH4 + (CH3)3CCH2
Reaction order:   2
Temperature:   703 - 743 K
Pressure:  6.67E-2 bar
Rate expression:   8.32x10-13 [cm3/molecule s] e-43069 [J/mole]/RT
Bath gas:   neo-C5H12
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
703 5.25E-16
725 6.56E-16
743 7.80E-16