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Accessibility information
Author(s):   Tsang, W.
Title:   Evidence for Strongly Temperature-Dependent A Factors in Alkane Decomposition and High Heats of Formation for Alkyl Radicals
Journal:   Int. J. Chem. Kinet.
Volume:   10
Year:   1978
Reference type:   Journal article
Squib:   1978TSA821

Reaction:   n-C4H10·C2H5 + ·C2H5
Reaction order:   1
Temperature:   1000 - 1200 K
Pressure:  0.67 - 1.60 bar
Rate expression:   2.51x1016 [s-1] e-343388 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 2.91E-2
1025 7.96E-2
1050 2.08E-1
1075 5.18E-1
1100 1.24E0
1125 2.86E0
1150 6.35E0
1175 1.36E1
1200 2.84E1