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Accessibility information
Author(s):   Astholz, D.C.; Troe, J.; Wieters, W.
Title:   Unimolecular processes in vibrationally highly excited cycloheptatrienes. I. Thermal isomerization in shock waves
Journal:   J. Chem. Phys.
Volume:   70
Year:   1979
Reference type:   Journal article
Squib:   1979AST/TRO5107

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   600 - 1400 K
Pressure:  2.00E-2 - 4.93 bar
Rate expression:   1.25x1014 [s-1] e-220334 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 8.23E-6
650 2.46E-4
700 4.53E-3
750 5.65E-2
800 5.14E-1
850 3.61E0
900 2.04E1
950 9.60E1
1000 3.87E2
1050 1.37E3
1100 4.31E3
1150 1.23E4
1200 3.21E4
1250 7.76E4
1300 1.75E5
1350 3.73E5
1400 7.52E5