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Title: Studies in Decarboxylation. Part 12. A Concerted Mechanism for the Gas-phase Pyrolysis of Cyclopropylacetic Acids
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979BIG/FET122
Reaction:
Bicyclo[3.1.0]hexane-1-acetic acid, α,α-dimethyl- → Other Products + CO2
Reaction order:
1
Temperature:
690 - 740
K
Pressure: 6.67E-2 - 0.67 bar
Rate expression:
9.2x1010 [±3.7x109 s-1] e-174604 [±6976 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 690 | 5.57E-3 |
| 700 | 8.61E-3 |
| 725 | 2.42E-2 |
| 740 | 4.36E-2 |