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Author(s):   Chuchani, G.; Hernandez, J.A.; Martin, I.
Title:   Neighboring olefinic double-bond participation in gas phase pyrolysis of some alkenyl chlorides
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):   1279 - 1286
Year:   1979
Reference type:   Journal article
Squib:   1979CHU/HER1279-1286

Reaction:   ClCH2CH2CH=CH21,3-Butadiene + HCl
Reaction order:   1
Temperature:   663 - 753 K
Pressure:  7.07E-2 - 0.29 bar
Rate expression:   6.17x1013 [s-1] e-223659 [±2237 J/mole]/RT
Uncertainty:   1.48000002
Bath gas:   ClCH2CH2CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
663 1.48E-4
675 3.04E-4
700 1.26E-3
725 4.75E-3
750 1.64E-2
753 1.89E-2