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Accessibility information
Author(s):   Clyne, M.A.A.; Holt, P.M.
Title:   Reaction kinetics involving ground X2II and excited A2Σ+ hydroxyl radicals. Part 2-Rate constants for reactions of OH X2II with halogenomethanes and halogenoethanes
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   75
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979CLY/HOL582

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1979CLY/HOL582   CH2F2 + ·OH·CHF2 + H2O  293 - 429   6.46E-12       1.66E04   7.86E-15  2
  1979CLY/HOL582   CH2F2 + ·OH·CHF2 + H2O  293 - 429   7.42E-12       1.75E04   6.46E-15  2
  1979CLY/HOL582   CH3CHF2 + ·OH → Other Products + H2O  293 - 417   2.92E-12       9977   5.21E-14  2
  1979CLY/HOL582   CHFCl2 + ·OH·CCl2F + H2O  241 - 423   2.09E-12       9977   3.73E-14  2
  1979CLY/HOL582   CHFCl2 + ·OH·CCl2F + H2O  293 - 413   4.78E-12       1.16E04   4.36E-14  2
  1979CLY/HOL582   CHF2Cl + ·OH·CClF2 + H2O  250 - 427   2.14E-12       1.50E04   5.10E-15  2
  1979CLY/HOL582   CHF2Cl + ·OH·CClF2 + H2O  294 - 426   9.55E-12       1.91E04   4.25E-15  2
  1979CLY/HOL582   CHF3 + ·OH·CF3 + H2O  296 - 430   1.65E-15       582   1.30E-15  2
  1979CLY/HOL582   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  293 - 417   3.32E-12       1.50E04   7.91E-15  2
  1979CLY/HOL582   CF3CH2Cl + ·OHH2O + CF3CHCl  263 - 427   5.25E-11       2.08E04   1.19E-14  2
  1979CLY/HOL582   CF3CH2Cl + ·OHH2O + CF3CHCl  294 - 427   3.89E-11       1.91E04   1.73E-14  2
  1979CLY/HOL582   CF3CHCl2 + ·OHH2O + CF3CCl2  293 - 429   1.78E-12       9977   3.17E-14  2
  1979CLY/HOL582   CF3CHCl2 + ·OHH2O + CF3CCl2  293 - 429   1.12E-12       8314   3.91E-14  2
  1979CLY/HOL582   C2F5H + ·OHC2F5 + H2O  294 - 441   1.69E-13       9146   4.22E-15  2
  1979CLY/HOL582   CHF2CHF2 + ·OHH2O + CHF2CF2  294 - 434   2.76E-12       1.50E04   6.56E-15  2
  1979CLY/HOL582   CH3CF3 + ·OHCF3CH2 + H2O  293 - 425   6.92E-11       2.66E04   1.50E-15  2
  1979CLY/HOL582   CH2FCHF2 + ·OH → Other Products + H2O  293 - 441   1.48E-12       8314   5.16E-14  2
  1979CLY/HOL582   CF3CH2F + ·OHH2O + CF3CHF  294 - 429   3.24E-12       1.50E04   7.71E-15  2

Search returned 18 records.