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Author(s):   Clyne, M.A.A.; Holt, P.M.
Title:   Reaction kinetics involving ground X2II and excited A2Σ+ hydroxyl radicals. Part 2-Rate constants for reactions of OH X2II with halogenomethanes and halogenoethanes
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   75
Year:   1979
Reference type:   Journal article
Squib:   1979CLY/HOL582

Reaction:   CF3CHCl2 + ·OHH2O + CF3CCl2
Reaction order:   2
Temperature:   293 - 429 K
Pressure:  2.00E-3 - 2.67E-3 bar
Rate expression:   1.78x10-12 [cm3/molecule s] e-9977 [±1696 J/mole]/RT
Uncertainty:   1.70000005
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 2.96E-14
300 3.25E-14
325 4.43E-14
350 5.76E-14
375 7.24E-14
400 8.85E-14
425 1.06E-13
429 1.08E-13