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Accessibility information
Author(s):   Cox, R.A.; Derwent, R.G.
Title:   Kinetics of chlorine oxide radical reactions using modulated photolysis. Part 1.-Disproportionation of ClO in the Cl2 photosensitised decomposition of ozone
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   75
Year:   1979
Reference type:   Journal article
Squib:   1979COX/DER1635

Reaction:   ClO + ClOClOO + ·Cl
Reaction order:   2
Reference reaction:   ClO + ClOO2 + Cl2
Reference reaction order:   2
Temperature:   278 - 318 K
Pressure:  1.01 bar
Rate expression:   8.71x101 e-11807 [±2004 J/mole]/RT
Uncertainty:   2.19000006
Bath gas:   O2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
278 5.27E-1
300 7.66E-1
318 1.00E0