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Author(s):   Cox, R.A.; Derwent, R.G.; Eggleton, A.E.J.; Reiid, H.J.
Title:   Kinetics of chlorine oxide radicals using modulated photolysis. Part 2.-ClO and ClOO radical kinetics in the photolysis of Cl2 + O2 + N2 mixtures
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   75
Year:   1979
Reference type:   Journal article
Squib:   1979COX/DER1648

Reaction:   O2 + ·ClClOO
Reaction order:   3
Reference reaction:   ClOOO2 + ·Cl
Reference reaction order:   2
Temperature:   290 - 310 K
Pressure:  3.33E-2 - 1.01 bar
Rate expression:   1.1x10-25 [cm3/molecule] (T/298 K)1.00 e26773 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
290 7.10E-21
300 5.08E-21
310 3.71E-21