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Accessibility information
Author(s):   Emel'kin, V.A.; Marusin, V.V.
Title:   Reaction of atomic nitrogen with CCl4, SiCl4, and BCl3
Journal:   Kinet. Catal.
Volume:   20
Year:   1979
Reference type:   Journal article
Squib:   1979EME/MAR685

Reaction:   CCl4 + N·CCl3 + NCl
Reaction order:   2
Temperature:   473 - 673 K
Pressure:  3.07E-3 - 5.73E-3 bar
Rate expression:   2.51x10-13 [cm3/molecule s] e-23031 [±690 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
473 7.18E-16
475 7.36E-16
500 9.85E-16
525 1.28E-15
550 1.63E-15
575 2.03E-15
600 2.48E-15
625 2.98E-15
650 3.54E-15
673 4.09E-15