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Author(s):   Martin, I.; Hernandez, J.A.; Rotinov, A.; Chuchani, G.
Title:   Evaluation of the Olefinic Double Bond Influence in the Unimolecular Honmogeneous Gas Phase Elimination of Alkenyl Acetates
Journal:   J. Phys. Chem.
Volume:   83
Year:   1979
Reference type:   Journal article
Squib:   1979MAR/HER3070

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1979MAR/HER3070   CH3C(O)OC(CH3)2CH2CH=CH2 → Other Products + CH3C(O)OH  513 - 693   3.89E13       1.70E05      1
  1979MAR/HER3070   CH3C(O)O(CH2)2CH=CH2CH3C(O)OH + 1,3-Butadiene  513 - 693   1.58E13       2.01E05      1
  1979MAR/HER3070   CH3C(O)O(CH2)3CH=CH2CH3C(O)OH + CH2=CHCH2CH=CH2  513 - 693   6.46E12       2.04E05      1
  1979MAR/HER3070   CH3C(O)OCH(CH3)CH2CH=CH2 → Other Products + CH3C(O)OH  513 - 693   2.19E12       1.78E05      1
  1979MAR/HER3070   CH3C(O)O(CH2)4CH=CH2CH3C(O)OH + CH2=CHCH2CH2CH=CH2  513 - 693   2.69E12       1.98E05      1

Search returned 5 records.