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Author(s):   Newman, C.G.; O'Neal, H.E.; Ring, M.A.; Leska, F.; Shipley, N.
Title:   Kinetics and mechanism of the silane decomposition
Journal:   Int. J. Chem. Kinet.
Volume:   11
Year:   1979
Reference type:   Journal article
Squib:   1979NEW/ONE1167

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Reference reaction:   CyclopropaneCH3CH=CH2
Temperature:   1020 - 1200 K
Pressure:  5.20 - 5.33 bar
Rate expression:   1.82x1015 [s-1] e-274378 [±13719 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 1.62E1
1025 1.90E1
1050 4.08E1
1075 8.48E1
1100 1.70E2
1125 3.32E2
1150 6.28E2
1175 1.16E3
1200 2.07E3