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Author(s):   Rossi, M.; Golden, D.M.
Title:   The absolute rate constant for the metathesis t-C4H9. + DI →’ C4H9D + I. and the heat of formation of the t-butyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   11
Year:   1979
Reference type:   Journal article
Squib:   1979ROS/GOL969

Reaction:   tert-C4H9 + DI(CH3)3CD + I
Reaction order:   2
Temperature:   644 - 722 K
Rate expression:   7.95x10-12 [cm3/molecule s] e-8896 [J/mole]/RT
Bath gas:   (tert-C4H9N)2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
644 1.51E-12
650 1.53E-12
675 1.63E-12
700 1.72E-12
722 1.81E-12