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Author(s):   Schug, K.P.; Wagner, H.Gg.; Zabel, F.
Title:   Gas phase α,α elimination of hydrogen halides from halomethanes. I. Thermal decomposition of chlorodifluoromethane, trifluoromethane, and trichloromethane behind shock waves
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   83
Year:   1979
Reference type:   Journal article
Squib:   1979SCH/WAG167

Reaction:   CHCl3CCl2 (X 1A1) + HCl
Reaction order:   1
Temperature:   1050 - 1380 K
Pressure:  2.40E-2 - 2.48 bar
Rate expression:   1.82x1014 [s-1] e-227817 [±11391 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 8.45E2
1075 1.55E3
1100 2.77E3
1125 4.81E3
1150 8.18E3
1175 1.36E4
1200 2.21E4
1225 3.52E4
1250 5.50E4
1275 8.45E4
1300 1.28E5
1325 1.90E5
1350 2.79E5
1375 4.03E5
1380 4.34E5