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Author(s):   Watson, R.T.; Ravishankara, A.R.; Machado, G.; Wagner, S.; Davis, D.D.
Title:   A kinetics study of the temperature dependence of the reactions of OH(2π) with CF3CHCl2, CF3CHClF, and CF2ClCH2Cl
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):   187 - 197
Year:   1979
Reference type:   Journal article
Squib:   1979WAT/RAV187-197

Reaction:   CF3CHCl2 + ·OHH2O + CF3CCl2
Reaction order:   2
Temperature:   245 - 375 K
Pressure:  5.33E-2 - 0.40 bar
Rate expression:   1.4x10-12 [±3.99x10-13 cm3/molecule s] e-9146 [±1280 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
245 1.57E-14
250 1.72E-14
275 2.56E-14
300 3.58E-14
325 4.74E-14
350 6.04E-14
375 7.45E-14