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Author(s):   Chiang, C.-C.; Skinner, G.B.
Title:   Resonance Absorption Measure- ments of Atom Concentrations in Reacting Gas Mixtures. 4. Measurements of H and D Atoms in Oxidationof H2, D2 and CD4
Journal:   Proc. Int. Symp. Shock Tubes Waves
Volume:   12
Year:   1980
Reference type:   Journal article
Squib:   1980CHI/SKI629

Reaction:   CD2O → Products
Reaction order:   2
Temperature:   1700 - 2200 K
Pressure:  1.41 - 3.71 bar
Rate expression:   7.47x10-8 [cm3/molecule s] e-300984 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1700 4.22E-17
1750 7.76E-17
1800 1.38E-16
1850 2.37E-16
1900 3.97E-16
1950 6.47E-16
2000 1.03E-15
2050 1.60E-15
2100 2.44E-15
2150 3.64E-15
2200 5.34E-15