Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Chuchani, G.; Martin, I.; Hernandez, J.A.; Rotinov, A.; Fraile, G.
Title:   Effects of Polar β Substituents in the Gas-Phase Pyrolysis of Ethyl Acetate Esters
Journal:   J. Phys. Chem.
Volume:   84
Year:   1980
Reference type:   Journal article
Squib:   1980CHU/MAR944

Reaction:   CH3C(O)O(CH2)2OCH3CH3C(O)OH + CH2=CHOCH3
Reaction order:   1
Temperature:   653 - 708 K
Pressure:  8.40E-2 - 0.28 bar
Rate expression:   1.1x1012 [s-1] e-203705 [±2037 J/mole]/RT
Uncertainty:   5.0
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
653 5.59E-5
675 1.90E-4
700 6.94E-4
708 1.03E-3