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Author(s):   Knoll, H.; Richter, G.; Schliebs, R.
Title:   On the Gas-Phase Free Radical Displacement Reaction CH3 + CD3COCD3 →’ CD3 + CH3COCD3
Journal:   Int. J. Chem. Kinet.
Volume:   12
Year:   1980
Reference type:   Journal article
Squib:   1980KNO/RIC623

Reaction:   (CH3N)2 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   (CD3)2CO + ·CH3 → Other Products + CH3D
Reference reaction order:   2
Temperature:   413 - 563 K
Pressure:  0.41 - 0.53 bar
Rate expression:   3.98x10-1 e13386 [±1206 J/mole]/RT
Uncertainty:   1.35000002
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
413 1.96E1
425 1.76E1
450 1.42E1
475 1.18E1
500 9.96E0
525 8.55E0
550 7.43E0
563 6.95E0