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Author(s):   Knoll, H.; Richter, G.; Schliebs, R.
Title:   On the Gas-Phase Free Radical Displacement Reaction CH3 + CD3COCD3 →’ CD3 + CH3COCD3
Journal:   Int. J. Chem. Kinet.
Volume:   12
Year:   1980
Reference type:   Journal article
Squib:   1980KNO/RIC623

Reaction:   (CD3)2CO + ·CH3 → Adduct
Reaction order:   2
Reference reaction:   (CD3)2CO + ·CH3 → Other Products + CH3D
Temperature:   413 - 563 K
Pressure:  0.41 - 0.53 bar
Rate expression:   5.25x10-14 [cm3/molecule s] e-48972 [±1962 J/mole]/RT
Uncertainty:   1.58000004
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
413 3.36E-20
425 5.02E-20
450 1.09E-19
475 2.16E-19
500 4.02E-19
525 7.04E-19
550 1.17E-18
563 1.50E-18